Crystalline materials: Twin behaviour and size.
نویسنده
چکیده
D anny de Vito would be happy to hear that for twin formation the paradigm 'smaller is stronger' still prevails. Twinning is a deformation process in crystals defined as the collective shearing of one portion of the crystal with respect to the rest. However, compared with plasticity based on dislocation glide, twinning has been scarcely studied in the deformation of metals. This is because twinning occurs (when slip by dislocation glide is suppressed) mostly for a few hexagonal-close-packed metals such as Ti, or at very low temperatures. Thus, twinning in metals has been considered of rather small technical importance. Furthermore, twinning is difficult to study as it occurs as a collective mechanism, and its origin and evolution in space and time remain puzzling. Writing in Nature, Yu et al. 1 now describe size effects on the deformation of small, micrometre-and submicrometre-sized Ti alloy crystals and, in doing so, provide new insights and questions relating to the deformation twinning process. It has long been known that size effects have a prominent role in the deformation and strength of metals. In the 1950s, it was observed that grain size has a strong impact on the strength of pure metals and alloys. Also, it was demonstrated impressively that specimen size is important and that small whiskers, presumably dislocation-free, can have very high strength. Over the decades, such size effects have been observed for many samples and testing conditions, including metal thin films and, most recently, for small single crystals in microcompression tests 2–4. Although not all details are understood, it is now recognized that these size effects relate to the confinement of the motion of dislocations and the availability of dislocations and dislocation sources 5. Moreover, it has been shown that nanoscale growth twins can lead to high-strength materials because the twins confine dislocation motion 6. This observation, however, is not to be confused with twinning as a deformation mechanism, which is discussed here. Intuitively, one might imagine that there is no size effect for twinning of a small single crystal, which can freely deform. It could be argued that a smaller crystal twins more easily because a smaller volume needs to be sheared compared with a large crystal. However, Yu et al. show that the opposite is true: the smaller the crystal, the greater the stress required for deformation twinning (Fig. 1). For submicrometre-sized crystals, the flow stress is found to be …
منابع مشابه
Growth and properties of coherent twinning superlattice nanowires.
Although coherent twin boundaries require little energy to form in nanoscale single crystals, their influence on properties can be dramatic. In recent years, some important steps forward have been made in understanding and controlling twinning processes at the nanoscale, making possible the fabrication of nanoengineered twinning superlattices in crystalline nanowires. These advances have opened...
متن کاملElastic deformation of twinned microstructures
Many crystalline materials exhibit twinned microstructures, where well-defined orientation relationships define the special symmetry between different, elastically anisotropic twin variants. When such twins are subjected to external loading, additional internal stresses necessarily occur at the twin boundaries in order to maintain compatibility. These compatibility stresses are constant inside ...
متن کاملGrains and grain boundaries in highly crystalline monolayer molybdenum disulphide.
Recent progress in large-area synthesis of monolayer molybdenum disulphide, a new two-dimensional direct-bandgap semiconductor, is paving the way for applications in atomically thin electronics. Little is known, however, about the microstructure of this material. Here we have refined chemical vapour deposition synthesis to grow highly crystalline islands of monolayer molybdenum disulphide up to...
متن کاملNear-ideal theoretical strength in gold nanowires containing angstrom scale twins
Although nanoscale twinning is an effective means to enhance yield strength and tensile ductility in metals, nanotwinned metals generally fail well below their theoretical strength limit due to heterogeneous dislocation nucleation from boundaries or surface imperfections. Here we show that Au nanowires containing angstrom-scaled twins (0.7 nm in thickness) exhibit tensile strengths up to 3.12 G...
متن کاملSynthesis, characterization and optical band gap of Lithium cathode materials: Li2Ni8O10 and LiMn2O4 nanoparticles
Li2Ni8O10 and LiMn2O4 Nanoparticles as cathode materials of lithium ion battery, were successfully synthesized using lithium acetate, nickel and manganese acetate as Li, Ni and Mn sources and stearic acid as a complexing reagent. The structure of the obtained products were characterized by FT-IR and XRD. The shape, size and distribution of the Li2Ni8O10 and LiMn2O4 nanoparticles were observed b...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Nature materials
دوره 9 4 شماره
صفحات -
تاریخ انتشار 2010